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|Title:||Gel-phase HR-MAS ¹H NMR spectroscopy as a probe for solid-tethered diimide rotaxanes and catenanes||Contributor(s):||Johnstone, Ken (author); Bampos, N (author); Sanders, JKM (author); Gunter, Maxwell John (author)||Publication Date:||2006||DOI:||10.1039/b602555b||Handle Link:||https://hdl.handle.net/1959.11/1327||Abstract:||The design and kinetically-controlled construction of a series of solid-tethered supramolecular systems utilising crown ether–naphthalene diimide host–guest chemistry are described.Functionalised polystyrene beads (ArgoGel-OH™) were utilised as the gel-phase solid support for the assembly of an appended diimide-crown catenane, and for a porphyrin-stoppered diimidecrown rotaxane. The structures of the resulting solid-tethered systems were probed using gelphase high-resolution magic-angle spinning (HR-MAS) ¹H NMR spectroscopy. The advantages of using this spectroscopic tool in conjunction with optical microscopy to probe solid-tethered supramolecular systems are discussed.||Publication Type:||Journal Article||Source of Publication:||New Journal of Chemistry, v.30, p. 861-867||Publisher:||Royal Society of Chemistry||Place of Publication:||Cambridge, England||ISSN:||1144-0546||Field of Research (FOR):||030302 Nanochemistry and Supramolecular Chemistry||Peer Reviewed:||Yes||HERDC Category Description:||C1 Refereed Article in a Scholarly Journal||Statistics to Oct 2018:||Visitors: 503
|Appears in Collections:||Journal Article|
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