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|Title:||Rayleigh Depolarization Ratios, Kerr Effects, Polarizabilities, and Hyperpolarizabilities of CH₃Br, CH₂Br₂, CHBr₃ and CBr₄.: Comparison of Experimental and ab Initio Calculated Polarizabilities||Contributor(s):||Blanch, Ewan (author); Keir, Roland (author); Ritchie, Geoffrey (author)||Publication Date:||2002||DOI:||10.1021/jp020003t||Handle Link:||https://hdl.handle.net/1959.11/1435||Abstract:||Improved equipment has been used to record the vapor-phase Rayleigh depolarization ratios and electrooptical Kerr effects of CH₃Br, CH₂Br₂, CHBr₃, and CBr₄ at elevated temperatures. The measurements yield experimental values of the anisotropic polarizabilities and the Kerr hyperpolarizabilities of these molecules. As well, Dougherty and Spackman's HUZ-SV(+sd+sp) basis set has been used to compute SCF and MP2-level polarizabilities, and these are compared with the experimental results.||Publication Type:||Journal Article||Source of Publication:||The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory, 106(16), p. 4257-4262||Publisher:||American Chemical Society||Place of Publication:||Washington, DC||ISSN:||1520-5215
|Field of Research (FOR):||020201 Atomic and Molecular Physics||Peer Reviewed:||Yes||HERDC Category Description:||C1 Refereed Article in a Scholarly Journal||Statistics to Oct 2018:||Visitors: 251
|Appears in Collections:||Journal Article|
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