Please use this identifier to cite or link to this item: https://une.intersearch.com.au/unejspui/handle/1959.11/1436
Title: Amide-appended porphyrins as scaffolds for catenanes, rotaxanes and anion receptors
Contributor(s): Gunter, Maxwell John (author); Farquhar, Sandra (author); Mullen, Kathleen (author)
Publication Date: 2004
DOI: 10.1039/b411583j
Handle Link: https://hdl.handle.net/1959.11/1436
Abstract: The synthesis of a porphyrin with an over-arching strap incorporating an isophthalamide unit produced both a porphyrin monomer with a potentially H-bonding receptor site, and a [2]catenane. Although both compounds exhibit fluxional behaviour, ¹H NMR and MS data was used to distinguish them, and was interpreted in terms of the dynamics of each system. The self-complementarity of the isophthalamide unit provides an ideal building block for assembling [2]pseudorotaxanes with similarly functionalised threads. This was illustrated by the self-assembly of a ruthenium–porphyrin stoppered rotaxane under thermodynamically controlled conditions, by simple mixing of the strapped porphyrin, a complementary thread unit containing an isophthalamide central unit and pyridine-attached ends, and a ruthenium carbonyl porphyrin. The strapped porphyrin was also shown to act as a receptor for chloride ion, and its binding ability with other H-bonding isophthalamide guests was found to be modulated by the presence of chloride ion. Chloride complexation was observed in both metallated and free base porphyrin monomers as well as the rotaxanes counterparts, but no anion binding was observed for the catenane.
Publication Type: Journal Article
Source of Publication: New Journal of Chemistry, 28(12), p. 1443-1449
Publisher: Royal Society of Chemistry
Place of Publication: United Kingdom
ISSN: 1144-0546
1369-9261
Field of Research (FOR): 030302 Nanochemistry and Supramolecular Chemistry
Peer Reviewed: Yes
HERDC Category Description: C1 Refereed Article in a Scholarly Journal
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